It first appeared as the opening track to the United Kingdom version of their album Aftermath. It was released as a single in the United States and peaked at number eight on the Billboard Hot singles chart in The song deals with the popularity of prescribed tranquilizers among housewives, and the potential hazards of overdose or addiction. Schaffner goes on to say "the Stones retaliated by zeroing in on all those harried middle-aged housewives incapable of getting through the day, or getting to sleep at night, without the help of their legally prescribed 'little yellow pills. The song begins with the line that is also heard as the last line in the repeated bridge section:.
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Pickett was inducted into the Rock and Roll Hall of Fame in , in recognition of his impact on songwriting and recording. Pickett was born March 18, in Prattville , Alabama,  and sang in Baptist church choirs. He was the fourth of 11 children and called his mother "the baddest woman in my book," telling historian Gerri Hirshey: "I get scared of her now.